Donald Trump seeks to use the same network to connect with female voters wary of his record.
Democratic nominee Harris will sit down with the conservative-leaning broadcaster in the battleground state of Pennsylvania, her most dramatic move yet as she carpets the airwaves to reach out to wavering Republican voters who have tired of Trump's dark rhetoric.
The White House race is neck-and-neck nationally and in swing states with less than three weeks to go, and both candidates are increasingly looking for ways to gain momentum.
Harris's appearance on Fox, where she will be quizzed by anchor Bret Baier in a show screening at 6:00 pm (2200 GMT), is a gamble as she tries to move the dial.
The vice president is aiming to neutralize Republican criticisms that she has avoided tough interviews, in which she can appear uncomfortable — but Fox is also the top-rated US cable news channel with a valuable audience.
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